If transactions have been processed as Authorize Only, they will be settled only when the order has been manually invoiced.
To Capture payments for an Authorized order, navigate to WooCommerce > Orders:
1. Find the Authorized order you wish to capture and click to open it.
2. In the Order Actions box, use the dropdown to select Capture Authorized Amount.
3. Click the Update button.
The payment will be captured, and an order note will be added.